Rapid anti-solvent vapor-assisted synthesis of CsPbBr3/Cs4PbBr6 microcrystals with high brightness and stability of green light emission

Journal of Materials Science - The CsPbBr3/Cs4PbBr6 perovskite composite material has received wide attention due to its good stability and photoelectric properties, and it is promising to appear...     

Structural damage and shear performance degradation of fiber–lime–soil under freeze–thaw cycling

The freeze–thaw cycling damages the soil structure, and the shear performance of soil are degraded. A series of tests on lime–soil(L–S) and fiber–lime–soil(F–L–S), including freeze–thaw test, the triaxial compression test, nuclear magnetic resonance (NMR) test and scanning electron microscope (SEM) test, were completed. The test results showed that fiber reinforcement changed the stress–strain behavior and failure pattern of soil. The cohesion and internal friction angle of soil gradually decreased with the increase of freeze–thaw cycles (F–T cycles). The pore radius and porosity of soil increased, while the micro pore volume decreased, and the small pore volume, medium pore volume and large pore volume increased, and the large pore volume had a little variation after 10 F–T cycles. The number of pores of F–L–S was less than L–S, demonstrating that the addition of fiber helped to reduce the pore volume. The interweaved fibers limited the development and the connection of cracks. By means of the spatial restraint effect of fiber on the soil and the friction action between fiber and soil, the shear performances and freeze–thaw durability of F–L–S better were than that of L–S.     

基于虚拟现实的复杂场景加载优化算法

目前大规模场景模型生成的需求量日益增加, 现提出了一种基于区域的自动 LOD (Levels Of Details)构建算法. 该算法基于动态网格简化算法, 在游戏设计制作的过程中, 游戏开发人员会经常需要对美工部门人员提供的模型进行优化. 为了可以使模型的面数得到简化, 并且不改变模型的外观. 当今流行的 LOD技术非常擅于处理这种情况, 判断模型与摄像机的距离如果超过一定范围之后, 自动调取不同层次的模型, 当模型距离摄像机很远的情况下使用面数低的模型替换高模, 这样可以提高帧率并且降低摄像机前的三角面以及顶点数从而减少渲染压力. 一般模型的简化分为静态和动态模型的简化.大部分情况下, 程序员会让美工部门提供几套不同面数的模型或者通过模型简化工具对高模进行减面并存成多个Mesh, 并在程序运行的时候, 根据模型与摄像机的距离远近动态的替换Mesh. 这是一种静态的方法.这里将尝试使用一种动态的网格简化和LOD技术相结合的方法. 这种新型算法的大大的简化了操作流程, 美术人员只需要提供一个模型, 程序员可以使用这种方法生成量级不同的低模, 根据摄像机与模型的远近自动的调取不同精度的模型.     

Surfactant-free electrochemical synthesis of fluoridated hydroxyapatite nanorods for biomedical applications

Fluoridated hydroxyapatite (FHA) [Ca₁₀(PO₄)₆F_x(OH)_2−x, x = 0–2] is believed to be a promising calcium phosphate (CaP) to replace pure hydroxyapatite (HA) for next-generation implants, owing to its better biocompatibility, higher antibacterial activity, and lower solubility. Notably, the shape and size of the CaP crystals play key roles in their performance and can influence their applications. One-dimensional (1D) FHA nanorods are important CaP materials which have been widely used in regenerative medicine applications such as restorative dentistry. Unfortunately, the traditional synthesis methods for FHA nanorods either employ surfactants or take a relatively long time. In this study, we aimed to propose a facile synthesis route to fabricate FHA nanorods without any surfactants using an electrochemical deposition method for the first time. This study focused on preparing FHA nanorods without the assistance of any surfactant, unlike the traditional synthesis methods, to avoid chemical impurities. FHA nanorods with lengths of 124–2606 nm, diameters of 28–211 nm, and aspect ratios of 4.4–21.8 were synthesized using the electrochemical method, followed by a heat treatment. For the as-synthesized FHA nanorods, the Ca/P ratio was 1.60 and the atomic concentration of F was 2.06 at.%. An ultrastructure examination revealed that each FHA nanorod possessed long-range order, good crystallinity, and a defect-free lattice with a certain crystallographic plane orientation along the whole rod. In short, we propose a novel, surfactant-free, cost-saving, and more efficient route to synthesize FHA nanorods which can be widely applied in multiple biomedical applications, including drug delivery, bone repair, and restorative dentistry.     

纳米抛光碳化硅压力对相变影响的分子动力学模拟

为了研究纳米抛光碳化硅时压力变化对表面的影响规律,建立了金刚石磨粒纳米抛光碳化硅的分子动力学模型,数值模拟了纳米尺度下的碳化硅抛光过程,具体分析了抛光压力线性增大过程中的配位数为1至6的原子数量的变化规律,揭示了线性改变抛光压力对被加工表面相变的影响规律,仿真结果表明:压力是诱导碳化硅相变的主要因素,当抛光压力增大时,发生相变的原子数增多,碳化硅的相变深度增加,其中配位数为1、2和4的原子数减少,配位数为3、5和6的原子数增多。     

A novel robot co-worker system for paint factories without the need of existing robotic infrastructure

This paper presents a human–robot co-working system to be applied to industrial tasks such as the production line of a paint factory. The aim is to optimize the picking task with respect to manual operation in a paint factory. The use of an agile autonomous robot co-worker reduces the time in the picking process of materials, and the reduction of the exposure time to raw materials of the worker improves the human safety. Moreover, the process supervision is also improved thanks to a better traceability of the whole process. The whole system consists of a manufacturing process management system, an autonomous navigation system, and a people detection and tracking system. The localization module does not require the installation of reflectors or visual markers for robot operation, significantly simplifying the system deployment in a factory. The robot is able to respond to changing environmental conditions such as people, moving forklifts or unmapped static obstacles like pallets or boxes. The system is not tied to specific manufacturing orders. It is fully integrated with the manufacturing process management system and it can process all possible orders as long as their components are placed into the warehouse. Real experiments to validate the system have been performed in a paint factory by a real holonomic platform and a worker. The results are promising from the evaluation of performance indicators such as exposure time of the worker to raw materials, automation of the process, robust and safe navigation, and the assessment of the end-user.     

NiMo/Cu-nanosheets/Ni-foam composite as a high performance electrocatalyst for hydrogen evolution over a wide pH range

We designed and fabricated non-precious and highly efficient electrocatalysts of nickelmolybdenum/copper-nanosheets/nickel-foam composites (NiMo/Cu-NS/NF) by step electrodepositions, combining with chemical oxidation method. The catalysts were charaterized by means of SEM, XRD and XPS spectra. Their electrocatalytic activities were assessed by hydrogen evolution reactions (HER) over a wide pH range, where acidic, neutral and alkaline electrolytes were used, respectively. Benefiting from the unique midlayer Cu nanosheets (NS) architecture and optimum Mo–Ni composition at the surface layer which led to high electronic conductivity and large electrochemically active surface area (ECSA), the NiMo/Cu-NS/NF-2 catalyst displayed superior electrocatalytic activities with low overpotentials of η₁₀ = 43, 86 and 89 mV in 0.5 M H₂SO₄, 1.0 M PBS and 1.0 M KOH electrolyte, respectively. Especially in the acidic condition, it exhibited the best electrocatalytic activity with smaller Tafel slope of 54 mV dec^?1 and higher exchange current density of 1.93 mA cm^?2.     

磁絮凝强化技术处理厌氧消化污泥脱水液

为满足后续生物处理单元对固体悬浮物（SS）和铁浓度的进水要求，采用磁絮凝强化技术对厌氧消化污泥脱水液进行预处理。通过正交试验和单因素试验，本文考察了混凝水力条件、聚合氯化铝（PAC）投加量、聚丙烯酰胺（PAM）投加量、磁粉投加量及药剂投加顺序对磁絮凝效果的影响。试验结果表明：磁絮凝强化技术在快搅300r/min（2min）、慢搅100r/min（15min）、静置10min时，依次投加磁粉（40mg/L）、PAC（30mg/L）、PAM（4mg/L）时处理效果最好。在此运行条件下，SS和Fe³⁺去除率分别为97.61%、98.24%、絮凝指数（FI值）取得最大值、zeta电位绝对值最小，絮凝效果最佳。与对照相比，磁絮凝强化技术对SS和Fe³⁺去除率分别可提高3.70%和10.82%，同时絮体最大沉降速度可提高33%。磁絮凝技术处理后的出水不仅可以满足后续生物处理单元对SS和铁浓度的要求，还可以有效提高磁絮凝体的沉降速度，减小沉淀时间，具有较好的实用价值。     

基于津沽文化脉络的文创产品创新发展策略研究

类比故宫博物院等优秀文创产品产业化发展思路对津沽文化脉络进行文化传承元素的有效梳理，结合产业化发展的活态传承与保护形式，以文创产品设计为研究载体，带动城市文化创新发展与文化自信，间接促进社会经济发展。通过总结天津非物质文化遗产的特性和产业化发展现状，对比分析不同领域文创产品设计案例。以市场需求定位设计层级，建立在设计层级基础上的产品创新设计理念，从升级保护技术的角度拓展产业化发展思路，结合数字化营销模式，适应现今智能化时代需求。总结了非遗文创产品在层级设计指导下的历史与文化，以及在现代与未来概念下的文化传承创新发展方向。进一步带动了天津文化产业发展，促进文化产业的良性循环，为天津传统文化产业化发展提出了切实可行的创新理念。